Chemistry » Chemical Bonding » Lewis Symbols and Structures

Summarizing Lewis Symbols and Structures

Key Concepts and Summary

Valence electronic structures can be visualized by drawing Lewis symbols (for atoms and monatomic ions) and Lewis structures (for molecules and polyatomic ions). Lone pairs, unpaired electrons, and single, double, or triple bonds are used to indicate where the valence electrons are located around each atom in a Lewis structure.

Most structures—especially those containing second row elements—obey the octet rule, in which every atom (except H) is surrounded by eight electrons. Exceptions to the octet rule occur for odd-electron molecules (free radicals), electron-deficient molecules, and hypervalent molecules.

Glossary

double bond

covalent bond in which two pairs of electrons are shared between two atoms

free radical

molecule that contains an odd number of electrons

hypervalent molecule

molecule containing at least one main group element that has more than eight electrons in its valence shell

Lewis structure

diagram showing lone pairs and bonding pairs of electrons in a molecule or an ion

Lewis symbol

symbol for an element or monatomic ion that uses a dot to represent each valence electron in the element or ion

lone pair

two (a pair of) valence electrons that are not used to form a covalent bond

octet rule

guideline that states main group atoms will form structures in which eight valence electrons interact with each nucleus, counting bonding electrons as interacting with both atoms connected by the bond

single bond

bond in which a single pair of electrons is shared between two atoms

triple bond

bond in which three pairs of electrons are shared between two atoms

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