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Electronic Structures of Anions

Electronic Structures of Anions

Most monatomic anions form when a neutral nonmetal atom gains enough electrons to completely fill its outer s and p orbitals, thereby reaching the electron configuration of the next noble gas. Thus, it is simple to determine the charge on such a negative ion: The charge is equal to the number of electrons that must be gained to fill the s and p orbitals of the parent atom.

Oxygen, for example, has the electron configuration 1s22s22p4, whereas the oxygen anion has the electron configuration of the noble gas neon (Ne), 1s22s22p6. The two additional electrons required to fill the valence orbitals give the oxide ion the charge of 2– (O2–).

Example: Determining the Electronic Structure of Anions

Selenium and iodine are two essential trace elements that form anions. Write the electron configurations of the anions.

Solution

Se2–: [Ar]3d104s24p6

I: [Kr]4d105s25p6

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